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no idea, had an exhaust shop do it years back when i made a custom exhaust for my 335i. as for what type, as long as it's high-temp paint you should be good. Rust-Oleum has one on Amazon for sale.
I never did the tips however, just the muffler. If really want a cleaner looks (especially if you are thinking about doing the exhaust tips), i'd say do it ONCE correctly and get it powdercoated (or buy a different set of tips prepainted). there are number of vendors here that sell gloss black tips for the OEM exhaust.
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